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Emerging chalcohalide materials for energy applications

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journal contribution
posted on 2023-03-20, 16:25 authored by Uma V. Ghorpade, Mahesh P. Suryawanshi, Martin A. Green, Tom Wu, Xiaojing Hao, KEVIN M. RYANKEVIN M. RYAN

Semiconductors with multiple anions currently provide a new materials platform from which improved functionality emerges, posing new challenges and opportunities in material science. This review has endeavored to emphasize the versatility of the emerging family of semiconductors consisting of mixed chalcogen and halogen anions, known as “chalcohalides”. As they are multifunctional, these materials are of general interest to the wider research community, ranging from theoretical/computational scientists to experimental materials scientists.This review provides a comprehensive overview of the development of emerging Bi- and Sb-based as well as a new Cu, Sn, Pb, Ag, and hybrid organic−inorganic perovskite-based chalcohalides. We first highlight the high-throughput computational techniques to design and develop these chalcohalide materials.We then proceed to discuss their optoelectronic properties,band structures, stability, and structural chemistry employing theoretical and experimental underpinning toward high-performance devices. Next, we present an overview of recent advancements in the synthesis and their wide range of applications in energy conversion and storage devices. Finally, we conclude the review by outlining the impediments and important aspects in this field as well as offering perspectives on future research directions to further promote the development of chalcohalide materials in practical applications in the future.

Funding

Multinary Compound Si, Ge and Sn Derived Nanocrystals: Composition, Shape and Heterostructure Control via Solution Methods (NanoIVCrystals)

Science Foundation Ireland

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NEILLSBAT - Nanostructured Electrodes and Ionic Liquid Electrolytes for Ultra High Energy Density Lithium Sulfur Batteries

Science Foundation Ireland

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Defect control for high-performance green kesterites energy materials

Australian Research Council

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An Emerging Ionic Chalcogenide Perovskites for Solar Energy Conversion

Australian Research Council

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History

Publication

Chemical Reviews, 2023 123 (1), 327-378

Publisher

American Chemical Society

Also affiliated with

  • Bernal Institute

Department or School

  • Chemical Sciences

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