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Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network

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posted on 2018-07-06, 07:40 authored by Shi-Qiang Wang, Qing‐Yuan Yang, Soumya Mukherjee, Daniel O'Nolan, Ewa Patyk-Kaźmierczak, Chen Kai-Jie, Mohana Shivanna, Claire A. Murray, Chiu C. Tang, Michael J. Zaworotko
A nonporous square lattice (sql) coordination network [Co(bipy)2(NCS)2]n (sql-1-Co-NCS) exhibits recyclable switching induced by CO2. The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage.

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Publication

Chemical Communications;54, pp. 7042-7045

Publisher

Royal Society of Chemistry

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peer-reviewed

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SFI

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© 2018 Royal Society of Chemistry. Personal use of this material is permitted. Permission from Royal Society of Chemistry must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works

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English

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    University of Limerick

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    Keywords

    isothermsfuelsgases

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    CC BY-NC-SA 1.0

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