Koupepidou_2023_Vapour.pdf (1.25 MB)
Water vapour induced structural flexibility in a square lattice coordination network
journal contribution
posted on 2023-11-16, 10:55 authored by Kyriaki KoupepidouKyriaki Koupepidou, Andrey BezrukovAndrey Bezrukov, Dominic CastellDominic Castell, DEBOBROTO SENSHARMADEBOBROTO SENSHARMA, Soumya MukherjeeSoumya Mukherjee, MICHAEL ZAWOROTKOMICHAEL ZAWOROTKOHerein, we introduce a new square lattice topology coordination network, sql-(1,3-bib)(ndc)-Ni, with three types of connection and detail its gas and vapour induced phase transformations. Exposure to humidity resulted in an S-shaped isotherm profile, suggesting potential utility of such materials as desiccants.
Funding
Ionic Ultramicroporous Polymer Adsorbents for Energy-efficient Purification of Commodity Chemicals
Science Foundation Ireland
Find out more...History
Publication
Chemical Communications, 2023Publisher
Royal Society of ChemistryOther Funding information
This work was financially supported by the Irish Research Council (IRCLA/2019/167) and Science Foundation Ireland (16/IA/4624). S. M. acknowledges an SFI-IRC Pathway award (21/PATH-S/9454) from the Science Foundation IrelandAlso affiliated with
- Bernal Institute
Sustainable development goals
- (4) Quality Education
External identifier
Department or School
- Chemical Sciences
