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Acetylene storage performance of [Ni(4,40-bipyridine)2(NCS)2]n, a switching square lattice coordination network†

Date
2022
Abstract
We report that the previously reported square lattice coordination network [Ni(4,40 -bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and bench-mark working capacity (185 cm 3 g 1 or 189 cm 3, 1–3.2 bar, 288 K) for acetylene storage.
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Description
peer-reviewed
Publisher
Royal Society of Chemistry
Citation
ChemCommun;
Collections
Bernal Institute
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Wang_2022_Acetylene.pdf
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Keywords
acetylene storage, lattice coordination
ULRR Identifiers
https://hdl.handle.net/10344/10921
 https://doi.org/10.34961/15108
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Funding Information
NSFC, Irish Research Council (IRC), Science Foundation Ireland (SFI)
Sustainable Development Goals
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