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High density germanium nanowire growth directly from copper foil by self induced solid seeding

Date
2011
Abstract
Herein, we describe the growth of highly dense germanium nanowire mats directly on copper foil by a self induced, solid seeded protocol. The existence of Cu3Ge tips on each of the nanowires indicates that growth proceeds via a solid catalyzed route, dependent on the in situ formation of the germanide intermediate. The nanowires show a tight diameter distribution and typically growth directions resulting from similarities in the d-spacings between the nanowire and the catalyst seed. The nanowires and substrates were characterized using transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD) scanning transmission electron microscopy (STEM), energy-dispersive X-ray spectroscopy (EDX) and electron backscatter diffraction (EBSD).
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Description
peer-reviewed
Publisher
American Chemical Society
Citation
Chemistry of Materials;23(21), pp. 4838-4843
Funding code
Funding Information
Science Foundation Ireland (SFI), Irish Governmentâ s Programme for Research in Third Level Institutions, Cycle 4, Irish Research Council for Science, Engineering and Technology (IRCSET)
Sustainable Development Goals
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