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Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network

Date
2018
Abstract
A nonporous square lattice (sql) coordination network [Co(bipy)2(NCS)2]n (sql-1-Co-NCS) exhibits recyclable switching induced by CO2. The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage.
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Description
peer-reviewed
Publisher
Royal Society of Chemistry
Citation
Chemical Communications;54, pp. 7042-7045
Collections
Bernal Institute
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Wang_2018_Recyclable.pdf
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Keywords
isotherms, fuels, gases
ULRR Identifiers
https://hdl.handle.net/10344/6939
 https://doi.org/10.34961/4728
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Funding Information
Science Foundation Ireland (SFI)
Sustainable Development Goals
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