Amino functionalised hybrid ultramicroporous materials that enable single-step ethylene purification from a ternary mixture

Zaworotko, Michael J.; Mukherjee, Soumya; Kumar, Naveen; Bezrukov, Andrey A.; Tan, Kui; Pham, Tony; Forrest, Katherine A.; Oyekan, Kolade; Qazvini, Omid T.; Madden, David G.; Space, Brian

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Amino functionalised hybrid ultramicroporous materials that enable single-step ethylene purification from a ternary mixture

Zaworotko, Michael J.; Mukherjee, Soumya; Kumar, Naveen; Bezrukov, Andrey A.; Tan, Kui; Pham, Tony; Forrest, Katherine A.; Oyekan, Kolade; Qazvini, Omid T.; Madden, David G.; Space, Brian

Date

2021

Abstract

Pyrazine-linked hybrid ultramicroporous (pore size 99.95% for SIFSIX-17-Ni) ethylene from a ternary equimolar mixture of ethylene, acetylene and CO2 thanks to coadsorption of the latter two gases. We attribute this performance to the very different binding sites in MFSIX-17-Ni versus SIFSIX-3-Zn.

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peer-reviewed

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John Wiley & Sons, Inc.

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Angewandte Chemie; 60 (19), pp. 10902-10909

Funding Information

Science Foundation Ireland (SFI), European Research Council (ERC), European Union (EU), U.S. Department of Energy

Amino functionalised hybrid ultramicroporous materials that enable single-step ethylene purification from a ternary mixture

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Sustainable Development Goals

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