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Hemilabile binding of acetylene in an amide-rich ultramicroporous MOF enables strong acetylene selectivity

Date
2024
Abstract
Thanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal–organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.
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Publisher
American Chemical Society
Citation
Inorganic Chemistry, 2024, 63 (27) pp. 12404–12408
Collections
Chemical Sciences
Bernal Institute
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Keywords
metal-organic framework (MOF), industrial processes, petrochemical industries, Chemical sciences
ULRR Identifiers
https://doi.org/10.34961/researchrepository-ul.27014761
 https://researchrepository.ul.ie/handle/10344/14880
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Funding Information
S.D. and S.K.G. thank IISER Pune and SERB (Project No. CRG/2022/001090) for research funding. S.M. acknowledges an SFI-IRC Pathway award (21/PATH-S/9454) from the Science Foundation Ireland. S.J.N. and M.V. acknowledge the Irish Center for High-End Computing (ICHEC). S.J.N. thanks Enterprise Ireland and the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement 847402 (ID: MF20210297).
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Article
Rights
https://creativecommons.org/licenses/by-nc-sa/4.0/
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