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[Cu(4â phenylpyridine)4(trifluoromethanesulfonate)2], a Werner complex that exhibits high selectivity for oâ xylene

Date
2020
Abstract
[Cu(4-phenylpyridine)4(trifluoromethanesulfonate)2] is a new Werner complex that exhibits switching behaviour between non-porous (apohost) and porous (guest-loaded) phases upon exposure to o-xylene but not when exposed to other C8 isomers. High o-xylene selectivity (>6) vs. the other C8 isomers was observed from binary mixtures, only the third occurrence across all sorbent types.
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Description
peer-reviewed
Publisher
Royal Society of Chemistry
Citation
Chemical Communications;56, pp. 1940-1943
Collections
Bernal Institute
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Zaworotko_2020_Cu.pdf
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Keywords
binary mixtures
ULRR Identifiers
https://hdl.handle.net/10344/8525
 https://doi.org/10.34961/4900
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Funding Information
Science Foundation Ireland (SFI)
Sustainable Development Goals
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