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Acetylene storage performance of [Ni(4,40-bipyridine)2(NCS)2]n, a switching square lattice coordination network†

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posted on 2022-01-17, 10:29 authored by Shi-Qiang Wang, Shaza Darwish, Xiao-Qing Meng, Ze Chang, Xian-He Bub, Michael J. Zaworotko
We report that the previously reported square lattice coordination network [Ni(4,40 -bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and bench-mark working capacity (185 cm 3 g 1 or 189 cm 3, 1–3.2 bar, 288 K) for acetylene storage.

Funding

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History

Publication

ChemCommun;

Publisher

Royal Society of Chemistry

Note

peer-reviewed

Other Funding information

NSFC, IRC, SFI

Language

English

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