posted on 2022-01-17, 10:29authored byShi-Qiang Wang, Shaza Darwish, Xiao-Qing Meng, Ze Chang, Xian-He Bub, Michael J. Zaworotko
We report that the previously reported square lattice coordination network [Ni(4,40 -bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and bench-mark working capacity (185 cm 3 g 1 or 189 cm 3, 1–3.2 bar, 288 K) for acetylene storage.
Funding
Variation in wood properties of different provenance of exotic loblolly pine for pulpwood and building lumber