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Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,40 -bipyridine)2(NCS)2]n
journal contribution
posted on 2023-07-07, 11:26 authored by Shi-Qiang WangShi-Qiang Wang, Shaza DarwishShaza Darwish, MICHAEL ZAWOROTKOMICHAEL ZAWOROTKOSwitching coordination networks (CNs) featuring stepped sorption isotherms that are accompanied by phase changes offer promise for gas storage and separation applications. However, their responsiveness to different adsorbates remains largely understudied. Herein, we report the variable switching behaviour of a previously known square lattice (sql) topology CN, [Ni(4,4′-bipyridine)2(NCS)2] (sql-1-Ni-NCS), with respect to nine gaseous adsorbates.
History
Publication
Chemical Communications, 2023, 59,pp. 559-562Publisher
Royal Society of ChemistryAlso affiliated with
- Bernal Institute
Department or School
- Chemical Sciences