Hemilabile binding of acetylene in an amide-rich ultramicroporous MOF enables strong acetylene selectivity
journal contribution
posted on 2024-10-29, 08:21 authored by Subhajit Dutta, Soumya MukherjeeSoumya Mukherjee, Sousa Javan NikkhahSousa Javan Nikkhah, Omid T. Qazvini, Gourab
K. Dam, Matthias VandichelMatthias Vandichel, Tarak Nath Mandal, Sujit K. GhoshThanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal–organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.
Funding
Ionic Ultramicroporous Polymer Adsorbents for Energy-efficient Purification of Commodity Chemicals
Science Foundation Ireland
Find out more...Career Development Fellowships in the National Technology Centre Programme
European Commission
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Publication
Inorganic Chemistry, 2024, 63 (27) pp. 12404–12408Publisher
American Chemical SocietyOther Funding information
S.D. and S.K.G. thank IISER Pune and SERB (Project No. CRG/2022/001090) for research funding. S.M. acknowledges an SFI-IRC Pathway award (21/PATH-S/9454) from the Science Foundation Ireland. S.J.N. and M.V. acknowledge the Irish Center for High-End Computing (ICHEC). S.J.N. thanks Enterprise Ireland and the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement 847402 (ID: MF20210297).Rights
© 2024 ACS This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsengineeringau.2c00025Also affiliated with
- Bernal Institute
External identifier
Department or School
- Chemical Sciences
