posted on 2018-04-25, 08:06authored byAlberto García, Mario Culebras, Maurice N. Collins, James J. Leahy
Currently, the most widely used binder in batteries is polyvinylidene fluoride (PVDF) with N-methyl-2-pyrrolidone (NMP) used as a solvent. This solvent is flammable and toxic. Here we focus on the suitability of using water soluble sodium alginate (Na-alginate) and sodium carboxymethyl cellulose (Na-CMC) as alternative biobased binder materials for the anodes of lithium ion batteries. It reduces the environmental impact of current manufacturing processes. However, control of the rheological characteristics of the binder whilst containing active and conductive additives is key for optimised processing. Here we perform stability and rheological measurements of Na-alginate and Na-CMC solutions containing varying amounts of graphite and carbon black used as active and conductive materials respectively. Comparing to the benchmark Na-CMC, the degree of flocculation shows that for the same concentration of binder in water, Na-alginate suspensions are more stable. The rheology measurements show that Na-alginate slurries have a higher viscosity than Na-CMC at a shear rate of 50 s-1 with that for a 1.5% of Na-alginate binder being 1.26 Pa·s while for Na-CMC it was for 0.20 Pa·s. The loss factor was lower for Na-Alginate, between 2 and 3 against between 2.9 and 3.3 for Na-CMC, showing a more developed network structure.
History
Publication
Journal of Applied Polymer Science;135 (17)
Publisher
Wiley and Sons Ldt
Note
peer-reviewed
Rights
This is the author version of the following article:
“Stability and rheological study of sodium carboxymethyl cellulose and alginate suspensions as binders for lithium ion batteries”
Journal of Applied Polymer Science
2018, 135 (17),
which has been published in final form at
https://doi.org/10.1002/app.46217
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
http://olabout.wiley.com/WileyCDA/Section/id-828039.html#terms