Zaworotko_2020_Cu.pdf (1.43 MB)
[Cu(4‐phenylpyridine)4(trifluoromethanesulfonate)2], a Werner complex that exhibits high selectivity for o‐xylene
journal contribution
posted on 2020-02-17, 15:04 authored by Adrianna M. Kałuża, Soumya Mukherjee, Shi-Qiang Wang, Daniel J. O'Hearn, Michael J. Zaworotko[Cu(4-phenylpyridine)4(trifluoromethanesulfonate)2] is a new Werner complex that exhibits switching behaviour between non-porous (apohost) and porous (guest-loaded) phases upon exposure to o-xylene but not when exposed to other C8 isomers. High o-xylene selectivity (>6) vs. the other C8 isomers was observed from binary mixtures, only the third occurrence across all sorbent types.
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Chemical Communications;56, pp. 1940-1943Publisher
Royal Society of ChemistryNote
peer-reviewedOther Funding information
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