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Pillar modularity in fsc topology hybrid ultramicroporous materials based upon tetra(4-pyridyl)benzene

Date
2022
Abstract
.Hybrid ultramicroporous materials (HUMs) are porous coordination networks composed of combinations of organic and inorganic linker ligands with a pore diameter of 10 for 1:99 C2H2/C2H4 and >5 for 1:1 C2H2/CO2. The approach taken, systematic variation of pillars with retention of structure, enables differences in selectivity to be attributed directly to the choice of the inorganic pillar. This study introduces fsc topology HUMs as a modular platform that is amenable to fine-tuning of structure and properties
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Description
Publisher
American Chemical Society
Citation
Crystal Growth and Design, 2022, 22, (9), pp. 5472–5480
Collections
Chemical Sciences
Bernal Institute
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Sensharma_2022_Pillar.pdf
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Keywords
benzene, hybrid materials, ligands, porous materials, single crystals, Chemical sciences
ULRR Identifiers
https://doi.org/10.34961/researchrepository-ul.24290923
 https://hdl.handle.net/10344/12299
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Funding Information
Sustainable Development Goals
(4) Quality Education
Type
Article
Rights
https://creativecommons.org/licenses/by-nc-sa/4.0/
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